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冯雄汉

发布日期:2016-05-23发表者:浏览次数:

姓名:冯雄汉  职称:教授    电话:(+)86-27-87280271

E-mailfxh73@mail.hzau.edu.cn


个人简介

     2003年12月获华中农业大学土壤学博士学位后留校任教。2007.5-2008.7受国家公派赴美Delaware大学Dr. Donald L. Sparks土壤环境化学实验室从事博士后研究。兼任中国土壤学会“土壤化学专业委员会”和“土壤环境专业委员会”委员,中国矿物岩石地球化学学会“矿物物理矿物结构专业委员会”和“环境矿物学专业委员会”委员。先后获湖北省杰出青年基金(2006)、高等学校全国优秀博士学位论文作者专项资金(2007)和霍英东青年教师基金(2008),2009年入选教育部新世纪优秀人才支持计划,2006年获全国优秀博士论文奖。担任国际期刊Clays and Clay Minerals副主编、Journal of Soils and Sedements、Geoderma Regional和Geochemical Transactions编委。


研究方向

从事土壤铁/锰等氧化物的结构和演化、磷土壤化学与界面过程,及其环境效应方面的研究,努力将前沿地球科学理论与技术方法应用到探索解决环境土壤学中的重要科学问题中。


承担的科研项目

(1)肥料磷在我国主要土壤中的转化过程及机制(2017.1-2020.12)

          国家重点研发计划重点专项“肥料磷素转化与高效利用机理”课题

(2)土壤31P核磁共振波谱分析(2016.1-2017.12)

          委托单位:中国科学院城市环境研究所(No. 0220160234)

(3)土壤中水铁矿的非生物形成及向晶质氧化铁的转化(2015.1-2018.12)

          国家自然科学基金面上项目(No.41471194)

(4)红壤区农田土壤中磷的形态与生物周转特性(2015-2016)

          中国科学院战略性先导科技专项(B类)子项目(No. XDB15020402-1)

(5)模拟表生环境下水钠锰矿氧化As(III)的Stirred-flow动力学研究(2012.12-2014.12)

          教育部留学回国人员科研启动基金

(6)铁/铝氧化物与几种土壤有机磷的界面反应特性及作用机制(2012.1-2015.12)国家自然科学基金(No.41171197)

          土壤锰细菌介导下钙锰矿的形成途径与机制(2010-2012)

(7)教育部“新世纪人才”计划(No. NCET-09-0399)

          土壤锰矿物氧化As(III)/Cr(III)化学动力学及反应机制研究(2010.1-2012.12)

(8)国家自然科学基金面上项目(No. 40971142)

          Mn(III)在土壤锰矿物氧化As(III)/Cr(III)中的作用与行为(2008.7-2011.7)霍英东高等院校青年教师基金(No. 111025)

(9)土壤中锰氧化物的生物与化学成矿耦合机制及其环境效应研究(2007-2011)

          高等学校全国优秀博士学位论文作者专项资金(No.200767)

(10)土壤锰矿物氧化Cr(III)的动力学过程与反应途径及Mn(III)的环境意义(2007-2008)

         湖北省自然科学基金计划青年杰出人才项目(No.2007ABB014)

(11)表生环境中钙锰矿化学生成条件和动力学的实验研究(2005.1-2007.12)

         国家自然科学基金青年基金(No. 40403009)

(12)模拟土壤环境条件下钙锰矿化学形成与转化的实验研究(2005.1-2007.12)

         教育部科学技术研究重点项目(No. 105122)


成果与论文

(一)SCI收录论文(*为通讯作者)

    1. Wang X M, Peng J, Liang X L, Zhu M Q, Lanson B, Wang L X, Liang X R, Liu F, Tan W F,Feng X H*. Effects of Mn2+, Ni2+and Cu2+on the formation and transformation of hydrosulfate green rust: reaction processes and underlying mechanisms.ACS Earth and Space Chemistry, 2019, in press (doi: 10.1021/acsearthspacechem.8b00187).

    2. Lan S, Wang X H, Yang P, Qin Z J, Zhu M Q, Zhang J, Liu F, Tan W F, Huang Q Y,Feng X H*. The catalytic effect of AQDS as an electron shuttle on Mn(II) oxidation to birnessite on ferrihydrite at circumneutral pH.Geochimica et Cosmochimica Acta, 2019, 247,175-190.

    3. Wu C K, Peacock C L, Lanson B, Yin H, Zheng L R, Chen Z J, Tan W F, Qiu G H, Liu F*,Feng X H*. Transformation of Co-containing birnessite to todorokite: Effect of Co on the transformation and implications for Co mobility.Geochimica et Cosmochimica Acta, 2019, 246, 21-40.

    4. Wan B, Yan Y P, Huang R X, Abdala D B, Liu F, TangY Z, Tan W F,Feng X H*.Formation of Zn-Al layered double hydroxides (LDH) during the interaction of ZnO nanoparticles (NPs) with γ-Al2O3.Science of The Total Environment, 2019, 650, 1980-1987.

    5. Tao L, Liu F B*, Liu C S,Feng X H, Gu L L, Wang B R, Wen S L, Xu M G. Mitigation of soil acidification through changes in soil mineralogy due to long-term fertilization in southern China.Catena, 2019, 174, 227-234.

    6. Yan Y P, Wan B, Jaisi DP, Yin H, Hu Z, Wang X M, ChenC M, Liu F,Tan W F,Feng, X H*.Effects ofmyo-inositol hexakisphosphate on Zn(II) sorption on γ-alumina: A mechanistic study.ACS Earth and Space Chemistry, 2018, 2, 787-796.

    7. Zeng L Q, Wan B, Huang R X, Yan Y P, Wang X M, Tan W F, Liu F,Feng X H*. Catalytic oxidation of arsenite and reaction pathways on the surface of CuO nanoparticles at a wide range of pHs.Geochemical Transactions, 2018, 19, 12.

    8. Feng X H, Wang P, Shi Z Q*, Kwon K D, Zhao H Y, Yin H, Lin Z, Zhu M Q, Liang X R, Liu F, Sparks D L. A quantitative model for the coupled kinetics of arsenic adsorption/desorption and oxidation on manganeses oxides.Environmental Science & Technology Letters, 2018,5, 175-180.

    9. Lan S, Ying H, Wang X M, Liu F, Tan W F, Huang Q Y, Zhang J.Feng X H*. Efficient catalytic As(III) oxidation on the surface of ferrihydrite in the presence of aqueous Mn(II).Water Research, 2018, 128, 92-101.

    10. Peng L F, Liu P Y,Feng X H, Wang Z M, Tao C, Liang Y Z, Lin Z, Shi Z Q*. Kinetics of heavy metal adsorption and desorption in soil: Developing a unified model based on chemical speciation.Geochimica et Cosmochimica Acta, 2018, 224, 282-300.

    11. Wang X M, Kubichi J D, Boily J F, Waychunas G A, Hu Y F,Feng X H, Zhu M Q*. Binding geometries of silicate species on ferrihydrite surfaces.ACS Earth and Space Chemistry, 2018, 2, 125-134.

    12. Wang X M, Wang Z M, Peak D, Tang Y D,Feng X H, Zhu M Q*. Quantification of coexisting inner- and outer-sphere complexation of sulfate on hematite surfaces.ACS Earth and Space Chemistry, 2018, 2, 387-398.

    13. Yan Y P, Wan B, Zhang Y Y, Zhang L M*, Liu F,Feng X H. In situ ATR-FTIR spectroscopic study of the co-adsorption of myo-inositol hexakisphosphate and Zn(II) on goethite.Soil Research, 2018, 56, 526-534.

    14. Liu H L, Wan B, Yan Y P*, Zhang Y Y, Cheng W,Feng X H. Adsorption of glycerophosphate on goethite (α-FeOOH): A macroscopicand infrared spectroscopic study.Journal of PlantNutrition and Soil Science, 2018, 181, 557-565.

    15. Li W,Feng X H, Song W, Guo M. Transformation of phosphorus in speciation and bioavailability during converting poultry litter to biochar. 2018,Frontiersin Sustainable Food Systems, 2018, 2, 20.

    16. Li Q, Du H H, Chen W L*, Hao J L, Huang Q Y*, Cai P,Feng X H, Aging shapes the distribution of copper in soil aggragate size fraction.Environmental Pollution, 2018, 233, 569-576.

    17. Qu M J, Li N, Li H D, Yang T W, Liu W, Yan Y P,Feng X H, Zhu D W*. Phytoextraction and biodegradation of atrazine by Myriophyllum spicatum and evaluation of bacterial communities involved in atrazine degradation in lake sediment.Chemosphere, 2018, 209: 439-448

    18. Qu C C, Ma M K, Chen W L, Cai P, Yu X Y,Feng X H, Huang Q Y. Modeling of Cd adsorption to goethite-bacteria composites.Chemosphere, 2018, 193, 943-950.

    19. Liang X R, Zhao Z X, Zhu M Q, Liu F, Wang L J, Yin H, Qiu G H, Cao F F, Liu X Q,Feng X H*. Self-assembly of birnessite nanoflowers by staged three-dimensional oriented attachment.Environmental Science: Nano, 2017, 4, 1656-1669.

    20. Wang X M, Peng J, Xu H H, Tan W F, Liu F, Huang Q Y,Feng X H*. Influences and mechanisms of As(V) concentration and environmental factors on hydrosulfate green rust transformation.Acta Chimica Sinica, 2017, 75(6): 608-616.

    21. Lan S, Wang X M, Xiang Q J, Yin H, Tan W F, Qiu G H, Liu F, Zhang J,Feng X H*. Mechanisms of Mn(II) catalytic oxidation on ferrihydrite surface and the formation of manganese (oxyhydr)oxides.Geochimica et Cosmochimica Acta, 2017, 211, 79-96.

    22. Yin H, Kwon K D, Lee J Y, Shen Y, Zhao H Y, Wang X M, Liu F, Zhang J,Feng X H*. Distinct effects of Al3+doping on the structure and properties of hexagonal turbostratic birnessite: a comparison with Fe3+doping.Geochimica et Cosmochimica Acta, 2017, 208, 268-284.

    23. Wan B, Yan Y P, Zhu M Q, Wang X M, Liu F, Tan W F,Feng X H*. Quantitative and spectroscopic investigations of the co-sorption of myo-inositol hexakisphosphate and cadmium(II) on to haematite.European Journal of Soil Science, 2017, 68, 374-383.

    24. Wan B, Yan Y P, Tang Y Z, Bai Y G, Liu F, Tan W F, Huang Q Y,Feng X H*. Effects of polyphosphates and orthophosphate on the dissolution and transformation of ZnO nanoparticles.Chemosphere, 2017,176, 255-265.

    25. Zhu Y H, Liang X R, Zhao H Y, Yin H, Liu M M, Liu F,Feng X H*. Rapid determination of the Mn average oxidation state of Mn oxides with a novel two-step colorimetric method.Analytical Methods, 2017, 9, 103-109.

    26. Wang X M, Hu Y F, Tang Y D, Yang P,Feng X H, Xu W Q, Zhu M Q. Phosphate and phytate adsorption andprecipitation on ferrihydrite surfaces.Environmental Science: Nano, 2017, 4, 2193-2204.

    27. Qin Z J, Xiang Q J, Liu F, Xiong J, Koopal L K, Zheng L R, Ginder-Vogel M, Wang M X,Feng X H, Tan W F, Yin H*. Local structure of Cu2+in Cu-doped hexagonal turbostratic birnessite and Cu2+stability under acid treatment.Chemical Geology, 2017, 466, 512-523.

    28. Li Y,Feng X H, Lu Z X, Yin H, Liu F, Xiang Q J*. Enhanced photocatalytic H2-production activity of C-dots modified g-C3N4/TiO2nanosheets composites.Journal of Colloid and Interface Science, 2017, 513, 866-876.

    29. Qu C C, Ma M K, Chen W L*, Cai P, Yu X Y,Feng X H, Huang Q Y*. Modeling of Cd adsorption to goethite-bacteria composites.Chemosphere, 2017, 193, 943-950.

    30. Zhang Q, Chen X D, Qiu G H, Liu F,Feng X H*. Size-controlled synthesis and formation mechanism of manganese oxide OMS-2 nanowires under reflux conditions with KMnO4and inorganic acids.Solid State Sciences, 2016, 55, 152-158.

    31. Zhao H Y, Zhu M Q, Li W, Elzinga E J, Villalobos M, Liu F, Zhang J,Feng X H*, Sparks D L. Redox Reactions between Mn(II) and Hexagonal Birnessite Change its Layer Symmetry.Environmental Science & Technology, 2016, 50, 1750-1758.

    32. Wang X M, Zhu M Q, Koopal L K, Li W, Xu W Q, Liu F, Zhang J, Liu Q S,Feng X H*, D L Sparks. Effects of crystallite sizes on the structure and magnetism of ferrihydrite.Environmental Science: Nano, 2016, 3, 190-202.

    33. Wan B, Yan Y P, Liu F, Tan W F, He J J,Feng X H*. Impacts of myo-inositol hexakisphosphate and phosphate adsorption on aggregation of CeO2nanoparticles: roles of pH and surface coverage.Environmental Chemistry, 2016, 13, 34-42.

    34. Wan B, Yan Y P, Liu F, Tan W F, He J J,Feng X H*. Surface speciation of myo-inositol hexakisphosphate adsorbed on TiO2nanoparticles and its impact on their colloidal stability in aqueous suspension: A comparative study with orthophosphate.Science of the Total Environment, 2016, 544, 134-142.

    35. Wan B, Yan Y P, Liu F, Tan W F, Chen X H,Feng X H*. Surface adsorption and precipitation of inositol hexakisphosphate on calcite: A comparison with orthophosphate.Chemical Geology, 2016, 421, 103-111.

    36. Feng X H*,Yan Y P, Wan B, Li W, Jaisi D P, Zheng L R, Zhang J, Liu F. Enhanced Dissolution and Transformation of ZnO Nanoparticles: The Role of Myo-inositol Hexakisphosphate.Environmental Science & Technology, 2016, 50, 5651-5660.

    37. Yin H, Tan N H, Liu C P, Wang J J, Liang X L, Qu M K,Feng X H, Qiu G H, Tan W F, Fan Liu*. The associations of heavy metals with crystalline iron oxides in the polluted soils around the mining areas in Guangdong Province, China.Chemosphere, 2016, 161, 181-189.

    38. Li W, Liang X L, An P F,Feng X H, Tan W F, Qiu G H, Hui Yin*, Fan Liu*. Mechanisms on the morphology variation of hematite crystals by Al substitution: The modification of Fe and O reticular densities.Scientific Reports, 2016, 6, 35960. DOI:10.1038/srep35960.

    39. Li W, Wang L J, Liu F, Liang XLFeng XH, Tan W F, Zheng LR, Yin H. Effects of Al3+doping on the structure and properties of goethite and its adsorption behavior towards phosphate.Journal of Environmental Science, 2016, 45, 18-27

    40. Ding H Y, Chen R F, Liu M M*, Huang R, Du Y M, Huang C, Yu X Y,Feng X H, Liu F. Preparation and characterization of biocompatible molecularly imprinted poly(ionic liquid) films on the surface of multi-walled carbon nanotubes.RSC Advances, 2016, 6, 43526-43538.

    41. Wang N, Hu H H, Huang Q Y, Cai P, Rong X M,Feng X H, Chen W L. Surface complexation modeling of Cd(II) sorption to montmorillonite, bacteria, and their composite.Biogeoscience, 2016, 13, 5557-5566.

    42. Du H H, Chen W L, Cai P, Rong X M,Feng X H, Huang Q Y. Competitive adsorption of Pb and Cd on bacteria-montmorillonite composite.Environmental Pollution, 2016, 218, 168-175.

    43. Feng X H*, Wang X M, Zhu M Q, Koopal Luuk, Xu H H, Wang Y, Liu F. Effects of phosphate and silicate on the transformation of hydroxycarbonate green rust into ferric (oxyhydr)oxides.Geochimica et Cosmochimica Acta, 2015, 171, 1-14.

    44. Zhao H Y, Liang X R, Yin H, Liu F, Tan W F, Qiu G H,Feng X H*. Formation oftodorokite from “c-disordered” H+-birnessites: the roles ofaverage manganese oxidation state andinterlayer cations.Geochemical Transactions, 2015, 16: 8.

    45. Wang X M, Gu C H,Feng X H*, Zhu M Q*. Sulfate local coordination environment in Schwertmannite.Environmental Science & Technology, 2015,49, 10440-10448.

    46. Wang X M, Lan S, Zhu M Q, Ginder-vogel M, Yin H, Liu F, Tan W F,Feng X H*. The presence of ferrihydrite promotes abiotic formation of manganese (oxyhydr)oxides.Soil Science Society of America Journal, 2015, 79, 1297-1305. doi:10.2136/sssaj2014.12.0502.

    47. Wang X M, Zhu M Q, Lan S, Ginder-Vogel M, Liu Fan,Feng X H*. Formation and secondary mineralization of ferrihydrite in the presence of silicate and Mn(II).Chemical Geology, 2015, 415, 37-46.

    48. Yan Y P, L K Koopal, Li W, Zheng A M, Yang J, Liu F,Feng X H*. Size-dependent sorption of myo-inositol hexakisphosphate and orthophosphate on nano-γ-Al2O3.Journal of Colloid and Interface Science, 2015, 451, 85-92.

    49. Yan Y P, L K Koopal, F Liu, Huang Q Y,Feng X H*. Desorption ofmyo -inositol hexakisphosphate and phosphate from goethite by different reagents.Journal of Plant Nutrition and Soil Science, 2015, 178, 878-887.

    50. Yin H, Dai X X, Zhu M Q, Li F H,Feng X H*, Liu F*.Fe-doped cryptomelane synthesized by refluxing at atmosphere: structure, properties and hotocatalytic degradation of phenol.Journal of Hazardous Materials, 2015, 296, 221-229.

    51. Barrow N J, Feng X H, Yan Y P. The specific adsorption of organic and inorganic phosphates by variable-charge oxides.European Journal of Soil Science, 2015, 66, 859-866.

     52. Yin H,Feng X H, Tan W F, Koopal L K, Hu T D, Zhu M Q*, Liu F*. Structure and properties of vanadium(V)-doped hexagonal turbostratic birnessite and its enhanced scavenging of Pb2+from solutions.Journal of Hazardous Materials, 2015, 288, 80-88.

     53. Zhao C S, Liu F*, Zhang Z, Rong X M, Tan W F,Feng X H, Chen X H. Microcalorimetric study on the growth and metabolism of a manganese(II)-oxidizing bacterium and its mutant strain.Geomicrobiology Journal, 2015, 32, 585-593.

    54. Zhang Z J, Lai J, Yin H,Feng X H, Tan W F, Liu F*. Absorption mechanisms of Cu2+on a biogenic bixbyite-like Mn2O3produced by Bacillus CUA isolated from soil.Geochemical Transactions, 2015, 16, 5.

    55. Yin H, Liu Y, Koopal L K,Feng X H, Chu S Q, Zhu M Q, Fan Liu*. High Co-doping promotes the transition of birnessite layer symmetry from orthogonal to hexagonal.Chemical Geology, 2015, 410, 12-20.

    56. Li H, Liu F, Zhu M Q,Feng X H, Zhang J, Yin H*. Structure and properties of Co-doped cryptomelane and its enhanced removal of Pb2+ and Cr3+ from wastewater. Journal of Environmental Sciences-China, 2015, 34, 77-85.

    57. Gao T Y, Shen Y G, Jia Z H, Qiu G H, Zhang Y S, Feng X H, Cai C F. Interaction mechanisms and kinetics of ferrous ion and hexagonal birnessite in aqueous systems.Geochemical Transactions, 2015, 16, 16.

    58. Gao T Y, Shi Y, Liu F, Zhang Y S,Feng X H, Tan W F, Qiu G H. Oxidation process of dissolvable sulfide by synthesized todorokite in aqueous systems.Journal of Hazardous Materials, 2015, 290, 106-116.

    59. Liu L H, Chen S L, Liu F, Xiang Q J,Feng X H, Qiu G H. Hydrothermal Preparation and Carbon Nanotube Modification of o-LiMnO2Cathode Materials for Lithium Battery.Chinese Journal of Inorganic Chemistry, 2015, 31(4), 703-709.

    60. Zhang Z J, Yin H, Tan W F, Koopal L K, Zheng L R,Feng X H*, Liu F*. Zn sorption to biogenic bixbyite-like Mn2O3produced by Bacillus CUA isolated from soil: XAFS study with constraints on sorption mechanism.Chemical Geology, 2014, 389, 82-90.

    61. Yan Y P, Wan B, Liu F, Tan W F, Liu M M,Feng X H*.Adsorption-desorption of myo-inositol hexakisphosphate on hematite.Soil Science, 2014, 179, 476-485.

    62. Yan Y P, Li W, Yang J, Zhang A M, Liu F,Feng X H*, Sparks, D L.Mechanism of myo-inositol hexakisphosphate sorption on amorphous aluminum hydroxide: spectroscopic evidence for rapid surface precipitation.Environmental Science & Technology, 2014,48, 6735-6742.

    63. Yan Y P, Liu F, Li W, Liu F,Feng X H*, Sparks, D L. Sorption and desorption characteristics of organic phosphates of different structures onto aluminum (oxyhydr)oxides.European Journal of Soil Science, 2014,65(2): 308-317.

    64. Yin H, Li H, Wang Y, Ginder-Vogel M, Qiu G H,Feng X H, Zheng L R, Liu F*. Effects of Co and Ni co-doping on the structure and reactivity of hexagonal birnessite.Chemical Geology, 2014, 381, 10-20.

    65. Chen S L, Cao F F, Liu F, Xiang Q J,Feng X H, Liu L H, Qiu G H. Facile hydrothermal synthesis and electrochemical properties of orthorhombic LiMnO2cathode materials for rechargeable lithium batteries.RSC Advances, 2014, 4, 13693-13703.

    66. Lang D, Xiang Q J, Qiu G H,Feng X H, and Liu F, Effects of crystalline phase and morphology on the visible light photocatalytic H2-production activity of CdS nanocrystals.Dalton Transactions. 2014, 43 (19), 7245-7253.

    67. Lang D, Liu F, Qiu, G H,Feng X H,Xiang Q J. Synthesis and visible-light photocatalytic performance of cadmium sulfide and oxide hexagonal nanoplates.Chempluschem. 2014,79(12),1726-1732.

    68. Sun H, Qiu G H, Wang Y,Feng X H, Yin H, Liu F. Effects of Co and Ni co-doping on the physicochemical properties of cryptomelane and its enhanced performance on photocatalytic degradation of phenol.Materials Chemistry and Physics, 2014, 148, 783-789.

    69. Wang X M, Li W*, Harrington R, Liu F, Parise J B,Feng X H*, Sparks D L. Effect offerrihydrite crystallite size on phosphate adsorption reactivity.Environmental Science & Technology, 2013,47, 10322-10331.

    70. Wang X M, Liu F, Tan W F,Feng X H*, Koopal K L. Transformation of hydroxycarbonate green rust into crystalline iron (hydr)oxides: influences of reaction conditions and underlyingmechanisms.Chemical Geology, 2013, 351(2): 57-65.

    71. Wang X M, Liu F, Tan W F, Li W,Feng X H*, Sparks D L. Characteristics of Phosphate Adsorption-Desorption onto Ferrihydrite: Comparison with Well-Crystalline Fe (hydr)oxides.Soil Science, 2013, 178, 1-11.

    72. Li W,Feng X H, Yan Y P, Sparks, D L, Phillips B L. Solid-state nuclear magic resonancespectroscopic study of phosphate sorption mechanisms on Aluminum (hydr)oxides.Environmental Science & Technology, 2013,47, 8308-8315.

    73. Yin H, Liu F,Feng X H, Hu T D, Zhen L R, Qiu G H, Koopal L K, Tan W F. Effects of Fe doping on the structures and properties of hexagonal birnessites-Comparison with Co and Ni doping.Geochimica et Cosmochimica Acta, 2013, 117, 1-15.

    74. Chen X D, Liu F, Zhao C S, Zhang Q,Feng X H, Chen X H. Adsorption of Mn-oxidizing bacteria on soil minerals and its impact on the bacterial growth and Mn(II) oxidation rate.Journal of Food, Agriculture & Environment, 2013, 11, 813-818.

    75. Chen S L, Liu F, Xiang Q J,Feng X H, Qiu G H. Synthesis of Mn2O3microstructures and their energy storage ability studies.Electrochimica Acta, 2013, 106, 360-371.

    76. Yin H, Tan W F, Zheng L R, Cui H J, Qiu G H, Liu F*,Feng X H*. Characterization of Ni-rich hexagonal birnessite and its geochemical effects on aqueous Pb2+/Zn2+and As(III).Geochimica et Cosmochimica Acta, 2012, 93, 47-62.

    77. Wang Y,Feng X H, Villalobos M, Tan W F, Liu F. Sorption behavior of heavy metals on birnessite: Relationship with its Mn average oxidation state and implications for types of sorption sites.Chemical Geology, 2012, 292-293:25-34.

    78. Wang M X, Tan W F,Feng X H, Koopal L K, Liu M M, Liu F. One-step synthesis of sea urchin-like -MnO2using KIO4as the oxidant and its oxidation of arsenite.Materials Letters, 2012,77, 60-62.

    79. Zhao W, Liu F,Feng X H, Tan W F, Qiu G H, Chen X H. Fourier transform infrared spectroscopy study of acid birnessites before and after Pb2+adsorption.Clay Minerals, 2012, 47, 191-204.

    80. Yin H, Liu F, Chen X H, Qiu G H,Feng X H, Tan W F. Synthesis of hureaulite by a reflux process at ambient temperature and pressure.Microporous & Mesoporous Materials, 2012, 153, 115-123.

    81. Shu J J, Li C, Liu M M, Liu H L,Feng X H, Tan W F, Liu F.Role of counteranions in sol-gel-derived alkoxyl-functionalized ionic-liquid-based organic-inorganic hybrid coatings for SPME.Chromatographia. 2012, 75, 23-24, 1421-1433.

    82. Zhang Q, Chen X D,Feng X H*, Qiu G H, Tan W F, Liu F*. Large-scale size-controlled synthesis of cryptomelane-type manganese oxide OMS-2 in lateral and longitudinal directions.Journal of Material Chemistry, 2011, 21, 5223-5225.

    83. Zhao W, Tan W F,Feng X H*, Liu F, Xie Y N, Xie Z. XAFS studies on surface coordination of Pb2+adsorbed on birnessites with different average oxidation states.Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2011, 379, 86-92.

    84. Zhang Q, Chen X D, Zheng C,Feng X H, Qiu G H, Tan W F and Liu F. Roles of manganese oxides in degradation of phenol under UV-Vis irradiation: Adsorption, oxidation, and photocatalysis.Journal of Environmental Sciences, 2011, 23, 1904-1910.

    85. Zhang Q, Xiao Z D,Feng X H, Tan W F, Qiu G H and Liu F. α-MnO2nanowires transformed from precursor δ-MnO2by refluxing under ambient pressure: The key role of pH and growth mechanism.Materials Chemistry and Physics,2011, 125, 678-685.

    86. Wei S Y, Liu F,Feng X H, Tan W F, Koopal L K. Formation and transformation of iron oxides-kaolinite associations in the presence of Fe(II).Soil Science Society of America Journal, 2011, 75, 45-55.

    87. Yin H,Feng X H, Qiu G H, Tan W F, Liu F. Characterization of Co-doped birnessites and application for removal of lead and arseniteJournal of Hazardous Materials,2011, 188, 341-349.

    88. Yin H, Liu F,Feng X H, Liu M M, Tan W F, Qiu G H. Co2+-exchange mechanism of birnessite and its application for the removal of Pb2+and As(III).Journal of Hazardous Material, 2011, 196, 318-326.

    89. Qiu G H, Li Q, Yu Y,Feng X H, Tan W F, Liu F. Oxidation behaviors and kinetics of sulfide by synthesized manganese oxide mineral.Journal of Soils and Sediments, 2011, 11, 1323-1333.

    90. Cui H J, Liu F, Tan W F,Feng X H.Effect of Cobalt-doped framework on formation of todorokite from layered manganese oxides with Mg2+/Co2+ions as template.Pedosphere, 2011, 21(6): 730-737.

    91. Zhou X, Xie P F, Wang J, Zhang B B, Liu M M, Liu H L,Feng X H.Preparation and characterization of novel crown ether functionalized ionic liquid-based solid-phase microextraction coatings by sol-gel technology.Journal of chromatography A, 2011, 1218: 3571-3580.

    92. Zhou X, Shao X, Shu J J, Liu M M, Liu H L,Feng X H, Liu F. Thermally stable ionic liquid-based sol-gel coating for ultrasonic extraction solid-phase microextraction-gas chromatography determination of phthalate esters in agricultural plastic films.Talanta, 2011, 89,129-135.

    93. Liu M M, Cao X H, Tan W F,Feng X H, Qiu G H, Chen X H, Liu F. Structural controls on the catalytic polymerization of hydroquinone by birnessites.Clays and Clay Minerals. 2011, 59, 525-537.

    94. 殷辉,刘凡,冯雄汉,谭文峰,邱国红,陈秀华,刘名茗.常压回流条件下拉锰矿的合成及其影响因素.无机材料学报, 2011, 26(3): 321-326.

    95. Feng X H, Zhu M Q, Ginder – Vogel M, Ni C, Sanjai J P, Sparks D L. Formation of nano-crystalline todorokite from biogenic Mn oxides.Geochimica et Cosmochimica Acta, 2010, 74, 3232-3245.

    96. Liu M M, Zhou X, Chen Y Y, Liu H L,Feng X H*, Qiu G H, Liu F, Zeng Z R. Innovative chemically bonded ionic liquids-based sol–gel coatings as highly porous, stable and selective stationary phases for solid phase microextraction.Analytica Chimica Acta, 2010, 683, 96-106.

    97. Cui H J,Feng X H, Tan W F, Zhao W, Wang M K, Tsao T, Liu F. Synthesis of a nanofibrous manganese oxide octahedral molecular sieve with Co(NH3)63+complex ions as template via a reflux method.Crystal Growth & Design,2010, 10, 3355-3362.

    98. Zhu M, Ginder-Vogel M, Parikh S J,Feng X Hand Sparks D L. Cation effects on the layer structure of biogenic Mn-oxides.Environmental Science & Technology, 2010, 44, 4465-4471.

    99. Zhao W, Wang Q Q, Liu F, Qiu G H, Tan W F,Feng X H.Pb2+adsorption on birnessite affected by Zn2+and Mn2+pre-treatments.Journal of Soils and Sediments,2010, 10, 870-878.

    100. Wang M X, Wang Y P, Tan W F, Liu F,Feng X H, Koopal L K. Effect of 1-1 electrolyte concentration on the adsorption/desorption of copper ion on synthetic birnessite .Journal of Soils and Sediments, 2010, 10, 879-885.

    101. Cui H J, Liu F,Feng X H, Tan W F, Wang M K. Aging promotes todorokite formation from layered manganese oxide at near-surface conditions.Journal of Soils and Sediments,2010, 10, 1540-1547.

    102. Qiu G H, Gao Z Y, Yin H,Feng X H, Tan W F, Liu F. Synthesis of MnPO4·H2O by refluxing process at atmospheric pressure.Solid State Science, 2010, 12, 808-813.

    103. Qiu G H, Wang J, Zhao W,Feng X H, Tan W F, Zhang Q, Liu F. Shape-controlled synthesis of nanostructure ramsdellite-type manganese oxide at atmospheric pressure,Chinese Journal of Chemistry, 2010,28, 2301-2307.

    104. Song C H, Li R Q, Liu F,Feng X H, Tan W F, Qiu G H. Cobalt-doped todorokites prepared by refluxing at atmospheric pressure as cathode materials for Li batteries.Electrochimica Acta,2010, 55, 9157-9165.

    105. 周欣,尚佳,刘名茗,刘汉兰,郝蓉,冯雄汉,刘凡.新型溶胶-凝胶离子液体固相微萃取探头的研制.化学学报2010, 68(17): 1749-1757.

    106. Cui H J, You L,Feng X H*, Tan W F, Qiu G H, Liu F.. Factors governing the formation of lithiophorite at atmospheric pressure.Clays and Clay Minerals,2009, 57, 353-360.

    107. Zhao W, Cui H J, Liu F, Tan W F,Feng X H*.Relationship between the amount of Pb(II) adsorbed by birnessites and their average oxidation state of Mn.Clays and Clay Minerals,2009, 57, 513-520.

    108. Cui H J,Feng X H, Tan W F, He J Z, Hu R G, Liu F. Synthesis of todorokite-type manganese oxide from Cu-buserite by controlling the pH at atmospheric pressure.Microporous and Mesoporous Materials, 2009, 117(1-2): 41-47.

    109. Zhao W,Feng X H, Tan W F, Liu F, Ding S W.Pb2+adsorption on birnessites with different average oxidation states of Mn and release characteristics of Mn2+/H+/K+.Journal of Environmental Sciences,2009, 21(4), 520-526.

    110. Cui H J, Qiu G H,Feng X H, Tan W F and Liu F. Birnessites with different average manganese oxidation states were synthesized, characterized, and transformed to todorokite at atmospheric pressure.Clays and Clay Minerals,2009, 57, 6, 715-724.

    111. 邱国红,杨丹,冯雄汉,张旭亮,陈秀华,刘名茗,刘凡*. Cu2+离子掺杂钙锰矿的合成及其电化学性质研究.高等学校化学学报, 2009, 30(8): 1481-1486.

    112. Cui H J, Liu X W, Tan W F,Feng X H*, Liu F, Ruan H D. Influence of Mn(III) availability on the phase transformation from layered buserite to tunnel-structured todorokite.Clays and Clay Minerals,2008, 56(4): 397-403.

    113. Zhang L M, Liu F, Tan W F,Feng X H, Zhu Y G He J Z. Microbial DNA extraction and analyses of soil iron-manganese nodules.Soil Biology and Biochemistry, 2008, 40(6):1364-1369.

    114. Qiu G H,Feng X H, Liu M M, Tan W F, Liu F. Investigation on Electrochemical Reduction Process of Nb2O5Powders in Molten CaCl2with Metallic Cavity Electrode.Electrochimica Acta,2008, 53, 4074-4081.

    115. Tan W F, Lu S J, Liu F,Feng X H, He J Z, Koopal L. Determination of point of zero charge of manganese oxides with different methods including an improved salt titration method.Soil Science. 2008, 173(4): 277-286.

    116. Feng X H, Zhai L M, Tan W F, Liu F, He J Z.Adsorption and redox reactions of heavy metals on synthesized Mn oxide minerals.Environmental Pollution, 2007, 147, 366-373.

    117. Feng X H, Zu Y Q, Tan W F, Liu F.Arsenite Oxidation by three types of manganese oxides.Journal of Environmental Sciences,2006, 18(2): 29-298.

    118. Feng X H, Zhai L M, Tan W F, Liu F, He J Z.The Controlling Effect of pH on Oxidation of Cr(III) by Manganese Oxide Minerals.Journal of Colloid and Interface Science,2006, 298, 258-266.

    119. Feng X H, Tan W F, Liu F, Ruan H D, He J Z. Oxidation of As(III) by several manganese oxide minerals in absence and presence of goethite.Acta Geologica Sinica-English Edition,2006, 80(2): 249-256

    120. Cui H J,Feng X H, Liu F, Tan W F. Effects of reaction conditions on the formation of todorokite at atmospheric pressure.Clays and Clay Minerals,2006, 54, 605-615.

    121. Feng X H, Tan W F, Liu F, Huang Q Y, Liu X W. Pathways of birnessite formation in alkali medium.Science in China, Ser. D,2005,48(9): 1438-1451.

    122. Cui H J,Feng X H*, Tan W F, Liu F, He J Z. Factors governing formation of todorokite at atmospheric pressure.Science in China, Ser. D,2005, 48(10): 1678-1689.

    123. Tan W F, Liu F,Feng X H, Huang Q Y, Li X Y.Adsorption and redox reactions of heavy metals on Fe–Mn nodules from Chinese soils.Journal of Colloid and Interface Science,2005, 284, 600-605.

    124. Feng X H, Tan W F, Liu F, Wang J B, Ruan H D. Synthesis of todorokite at atmospheric pressure.Chemistry of Materials,2004, 16, 4330-4336.

    125. Feng X H, Zu Y Q, Tan W F, Liu F. Preparative parameter effects on synthesis of birnessite by O2oxidation.Pedosphere, 2004, 14(1): 63-70.

    126. Feng X H, Liu F, Tan W F, Liu X W. Synthesis of birnessite by O2oxidation in alkali medium: effects of synthesis conditions.Clays and Clay Minerals,2004, 52, 240-250.

    127. Feng X H, Liu F, Tan W F, Liu X W, Hu H Q.Synthesis of todorokite by refluxing process and its primary characterization.Science in China, Ser. D,2004, 47(8): 760-768.

(二)其它专著、教材

    1. Feng X H,Li W, Zhu M Q, D L Sparks (eds.),Advances in the Environmental Biogeochemistry of Manganese Oxides.American Chemical Society, USA,2015. DOI: 10.1021/bk-2015-1197.

    2. Feng X H, Zhao H Y, Liu F, Cui H J, Tan W F, Li W (2015). Transformation from phyllomanganates to todorokite under various conditions: A review and implication for formation pathway of natural todorokite. In: Feng X H, Li W, Zhu M Q, D L Sparks (eds.),Advances in the Environmental Biogeochemistry of Manganese Oxides. American Chemical Society, USA, pp 107-134. DOI: 10.1021/bk-2015-1197.ch006.

    3. Feng X H, Xu J L, Liu F, Tan W F (2009). Kinetics of As(III) and Cr(III) oxidation by alkaline birnessites with various average oxidation states.In: Xu J M, Huang P M (eds.),Molecular environmental soil science at the interfaces in the earth’s critical zone. Zhejiang University Press & Spinger, Hangzhou, China. Pp. 85-87.

(三)专利

    1. 冯雄汉,刘凡,谭文峰,贺立源,王贻俊.一种3×3隧道构造锰氧八面体分子筛的制备方法.中国发明专利, ZL.02147839.2,授权公告日:2005-7-27.

    2. 刘名茗,周欣,陈颍漪,冯雄汉,刘凡.溶胶-凝胶离子液体固相微萃取头及其制备方法.中国发明专利, ZL.20101026369.8,授权公告日2012-6-27.

    3. 邱国红,殷辉,刘凡,冯雄汉,谭文峰,刘名茗,陈秀华.一种锰磷酸盐材料的制备方法,中国发明专利申请,申请日, 2010.7,申请号: 201010223079.6.

    4. 邱国红,刘凡,陈述林,冯雄汉,向全军.一种锂二次电池正极材料LiMnO2的制备方法,中国发明专利, ZL.201310259834.X,授权公告日2016-12-28.

    5. 刘名茗,皮江燕,林丹妮,王小洁,冯雄汉,刘凡.牛血清白蛋白表面分子印迹聚合物及其制备方法,中国发明专利, ZL.201510134432.6,授权公告日2016-1-20.

    6. 刘名茗,王小洁,皮江燕,黄蓉,杜亚媚,冯雄汉,刘凡.碳纳米管表面溶菌酶分子印迹聚合物及其制备方法,中国发明专利, ZL.201510395854.9,授权公告日2016-6-8.